Flammable and Combustible Liquids #1
Over the next four weeks on Wednesdays we are going to discuss how to safely use and store both flammable and combustible liquids, but first lets define what they are.
Flammable Classifications
A flammable liquid has a flash point below 100°F. (The flash point is the temperature at which the liquid gives off enough vapors to ignite.) Flammable liquids are also called Class I liquids. Class I liquids are further divided into IA, IB, or IC depending on their flash points and boiling points.
· Class IA liquids have flashpoints below 73°F (22.8°C) and a boiling point below 100° (37.8°C). Liquids in this category include ethyl ether, isoprene, pentane, and petroleum ether.
· Class IB includes liquids having flashpoints below 73°F (22.8°C) and a boiling point at or above 100°F (37.8°C). Examples of liquids falling in this category include acetone, benzene, denatured alcohol, gasoline (all), isopropyl alcohol, methyl ethyl ketone (MEK), and octane.
· Class IC includes liquids having flashpoints at or above 73°F (22.8°C) and below 100°F (37.8°C). Liquids in this category include amyl acetate, banana oil (isoamyl acetate), styrene, and turpentine.
Combustible Classifications
Combustible liquids have flashpoints above 100°F and below 200°F combustible liquids are Class II or Class III liquids. The class description depends on a liquid flash point. Lower numbers and letters reflect a greater hazard.
· Class II includes liquids with flashpoints at or above 100°F (37.8°C) and below 140°F (60°C), except any mixture having components with flashpoints of 200°F (93.3°C) or higher. Class II liquids include diesel fuel, fuel oils, kerosene, and mineral spirits.
· Class III liquids are those with flashpoints at or above 140°F (60°C). Included in this category are aniline, glycol, glycerine, and butyl “cellosolve.” This class is subdivided into two subclasses.
· Class IIIA includes liquids with flashpoints at or above 140°F (60°C) and below 200°F (93.3°C), except any mixture having components with flashpoints of 200°F (93.3°C) or higher when the volume makes up 99 percent or more of the total.
· Class IIIB includes liquids with flashpoints at or above 200°F (93.3°C).
Since many flammables can ignite at temperatures at or below room temperature, they are much more dangerous than combustibles. Combustibles become much more dangerous when they are heated. If a combustible liquid is heated to within 30°F of its flash point, it must be treated like the next lower (more dangerous) class of liquid.

